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Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus

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Reichl, Stephan ; Mädl, Eric ; Riedlberger, Felix ; Piesch, Martin ; Balázs, Gábor ; Seidl, Michael ; Scheer, Manfred
License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 21 Apr 2022 15:03


The synthesis of phosphines is based on white phosphorus, which is usually converted to PCl3, to be afterwards substituted step by step in a non-atomic efficient manner. Herein, we describe an alternative efficient transition metal-mediated process to form asymmetrically substituted phosphines directly from white phosphorus (P4). Thereby, P4 is converted to [Cp*Fe(η5-P5)] (1) (Cp* = η5-C5(CH3)5) ...


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