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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-523978
- DOI to cite this document:
- 10.5283/epub.52397
Abstract
The oxidation of [(Cp*Mo)2(μ,η6:η6-P6)] (1) with halogens or halogen sources was investigated. The iodination afforded the ionic complexes [(Cp*Mo)2(μ,η3:η3-P3)(μ,η1:η1:η1:η1-P3I3)][X] (X=I3−, I−) (2) and [(Cp*Mo)2(μ,η4:η4-P4)(μ-PI2)][I3] (3), while the reaction with PBr5 led to the complexes [(Cp*Mo)2(μ,η3:η3-P3)(μ-Br)2][Cp*MoBr4] (4) [(Cp*MoBr)2(μ,η3:η3-P3)(μ,η1-P2Br3)] (5) and ...

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