Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo) 2 (μ,η 6 :η 6 ‐P 6 )]: Snapshots on the Reaction Progress

URN to cite this document:: urn:nbn:de:bvb:355-epub-523978
DOI to cite this document:: 10.5283/epub.52397

Garbagnati, Anna ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred

Preview

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
PDF - Published Version
(5MB)

Date of publication of this fulltext: 14 Jun 2022 08:33

Alternative links to fulltext:DOI Publisher

Details

Preview

Export bibliographical data

Abstract

The oxidation of [(Cp*Mo)2(μ,η6:η6-P6)] (1) with halogens or halogen sources was investigated. The iodination afforded the ionic complexes [(Cp*Mo)2(μ,η3:η3-P3)(μ,η1:η1:η1:η1-P3I3)][X] (X=I3−, I−) (2) and [(Cp*Mo)2(μ,η4:η4-P4)(μ-PI2)][I3] (3), while the reaction with PBr5 led to the complexes [(Cp*Mo)2(μ,η3:η3-P3)(μ-Br)2][Cp*MoBr4] (4) [(Cp*MoBr)2(μ,η3:η3-P3)(μ,η1-P2Br3)] (5) and ...