Halogenation of the Hexaphosphabenzene Complex [(Cp*Mo) 2 (μ,η 6 :η 6 ‐P 6 )]: Snapshots on the Reaction Progress

URN to cite this document:: urn:nbn:de:bvb:355-epub-523978
DOI to cite this document:: 10.5283/epub.52397

Garbagnati, Anna ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred

Preview

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
PDF - Published Version
(5MB)

Date of publication of this fulltext: 14 Jun 2022 08:33

Alternative links to fulltext:DOI Publisher

This publication is part of the DEAL contract with Wiley.

Details

Preview

Indexed in

Export bibliographical data

Abstract

The oxidation of [(Cp*Mo)(2)(mu,eta(6):eta(6)-P-6)] (1) with halogens or halogen sources was investigated. The iodination afforded the ionic complexes [(Cp*Mo)(2)(mu,eta(3):eta(3)-P-3)(mu,eta(1):eta(1):eta(1):eta(1)-P3I3)][X] (X=I-3(-), I-) (2) and [(Cp*Mo)(2)(mu,eta(4):eta(4)-P-4)(mu-PI2)][I-3] (3), while the reaction with PBr5 led to the complexes ...