Single Crystal X‐Ray Structure Analyses of Binary and Ternary Compounds A 49 Tl 108+x ( A =K, Rb, Cs; x=0–1.76) Related to the K 49 Tl 108 Type Structure

URN to cite this document:: urn:nbn:de:bvb:355-epub-525165
DOI to cite this document:: 10.5283/epub.52516

Schwinghammer, Vanessa F. ; Janesch, Melissa ; Kleemiss, Florian

; Gärtner, Stefanie

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Date of publication of this fulltext: 28 Jun 2022 04:46

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Abstract

The structural chemistry of alkali metal thallides shows a broad range of type structures. At an alkali metal : thallium proportion A : Tl 1 : 2 the perceived dependency on the alkali metal involved is conspicuous. Two main structure types are reported with A15Tl27 (A=K, Rb, Cs) and K49Tl108. The compound K49K108 with a 3-dimensional Tl-substructure has been known since 1993 from Cordier and ...