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Single Crystal X‐Ray Structure Analyses of Binary and Ternary Compounds A 49 Tl 108+x ( A =K, Rb, Cs; x=0–1.76) Related to the K 49 Tl 108 Type Structure

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Schwinghammer, Vanessa F. ; Janesch, Melissa ; Kleemiss, Florian ; Gärtner, Stefanie
Date of publication of this fulltext: 28 Jun 2022 04:46

This publication is part of the DEAL contract with Wiley.


The structural chemistry of alkali metal thallides shows a broad range of type structures. At an alkali metal : thallium proportion A : Tl 1 : 2 the perceived dependency on the alkali metal involved is conspicuous. Two main structure types are reported with A(15)Tl(27) (A=K, Rb, Cs) and K49Tl108. The compound K49K108 with a 3-dimensional Tl-substructure has been known since 1993 from Cordier and ...


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