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An NHC‐Stabilized H₂GeBH₂ Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains

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Ackermann, Matthias T. ; Seidl, Michael ; Wen, Fuwei ; Ferguson, Michael J. ; Timoshkin, Alexey Y. ; Rivard, Eric ; Scheer, Manfred

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Date of publication of this fulltext: 26 Jul 2022 08:53


The synthesis, characterization and reactivity studies of the NHC-stabilized complex IDipp ⋅ GeH2BH2OTf (1) (IDipp=1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) are reported. Nucleophilic substitution of the triflate (OTf) group in 1 by phosphine or arsine donors provides access to the cationic group 13/14/15 chains [IDipp ⋅ GeH2BH2ERR1R2]+ (2 E=P; R, R1=H; R2=tBu; 3 E=P; R=H; R1, R2=Ph; ...


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