The Missing Parent Compound [(C 5 H 5 )Fe(η 5 ‐P 5 )]: Synthesis, Characterization, Coordination Behavior and Encapsulation

URN to cite this document:: urn:nbn:de:bvb:355-epub-528193
DOI to cite this document:: 10.5283/epub.52819

Heinl, Claudia ; Peresypkina, Eugenia

; Balázs, Gábor

; Mädl, Eric ; Virovets, Alexander V. ; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 26 Aug 2022 12:10

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Abstract

The so far missing parent compound of the large family of pentaphosphaferrocenes [CpFe(η5-P5)] (1 b) was synthesized by the thermolysis of [CpFe(CO)2]2 with P4 using the very high-boiling solvent diisopropylbenzene. It was comprehensively characterized by, inter alia, NMR spectroscopy, single crystal X-ray structure analysis, cyclic voltammetry and DFT computations. Moreover, its coordination ...