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The Missing Parent Compound [(C 5 H 5 )Fe(η 5 ‐P 5 )]: Synthesis, Characterization, Coordination Behavior and Encapsulation

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Heinl, Claudia ; Peresypkina, Eugenia ; Balázs, Gábor ; Mädl, Eric ; Virovets, Alexander V. ; Scheer, Manfred
Date of publication of this fulltext: 26 Aug 2022 12:10

This publication is part of the DEAL contract with Wiley.


The so far missing parent compound of the large family of pentaphosphaferrocenes [CpFe(eta(5)-P-5)] (1 b) was synthesized by the thermolysis of [CpFe(CO)(2)](2) with P-4 using the very high-boiling solvent diisopropylbenzene. It was comprehensively characterized by, inter alia, NMR spectroscopy, single crystal X-ray structure analysis, cyclic voltammetry and DFT computations. Moreover, its ...


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