Go to content
UR Home

Synthesis and Redox Chemistry of a Homoleptic Iron Arsenic Prismane Cluster

URN to cite this document:
urn:nbn:de:bvb:355-epub-528477
DOI to cite this document:
10.5283/epub.52847
Riesinger, Christoph ; Dütsch, Luis ; Scheer, Manfred
Date of publication of this fulltext: 06 Sep 2022 05:40


Abstract

The redox chemistry of the homoleptic iron prismane cluster [{Cp*Fe}3(μ3,η4:4:4-As6)] (A, Cp*=C5Me5) is investigated both electrochemically and synthetically. While its first oxidation leads to the diamagnetic species [{Cp*Fe}3(μ3,η4:4:4-As6)][X] ([1][TEF], [1][FAl], [TEF]−=[Al{OC(CF3)3}4]−, [FAl]−=[FAl{O(1-C6F5)C6F10}3]−), the second oxidation yields the paramagnetic ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -4239

Contact persons