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Synthesis and Redox Chemistry of a Homoleptic Iron Arsenic Prismane Cluster

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Riesinger, Christoph ; Dütsch, Luis ; Scheer, Manfred
Date of publication of this fulltext: 06 Sep 2022 05:40

This publication is part of the DEAL contract with Wiley.


The redox chemistry of the homoleptic iron prismane cluster [{Cp*Fe}(3)(mu(3),eta(4:4:4)-As-6)] (A, Cp*=C5Me5) is investigated both electrochemically and synthetically. While its first oxidation leads to the diamagnetic species [{Cp*Fe}(3)(mu(3),eta(4:4:4)-As-6)][X] ([1][TEF], [1][FAl], [TEF](-)=[Al{OC(CF3)(3)}(4)](-), [FAl](-)=[FAl{O(1-C6F5)C6F10}(3)](-)), the second oxidation yields the ...


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