Synthesis and Redox Chemistry of a Homoleptic Iron Arsenic Prismane Cluster

URN to cite this document:: urn:nbn:de:bvb:355-epub-528477
DOI to cite this document:: 10.5283/epub.52847

Riesinger, Christoph ; Dütsch, Luis ; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 06 Sep 2022 05:40

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Abstract

The redox chemistry of the homoleptic iron prismane cluster [{Cp*Fe}3(μ3,η4:4:4-As6)] (A, Cp*=C5Me5) is investigated both electrochemically and synthetically. While its first oxidation leads to the diamagnetic species [{Cp*Fe}3(μ3,η4:4:4-As6)][X] ([1][TEF], [1][FAl], [TEF]−=[Al{OC(CF3)3}4]−, [FAl]−=[FAl{O(1-C6F5)C6F10}3]−), the second oxidation yields the paramagnetic ...