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Visible Light-Enhanced C−H Amination of Cyclic Ethers with Iminoiodinanes

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Jurberg, Igor D. ; Nome, Rene A. ; Crespi, Stefano ; Atvars, Teresa D. Z. ; König, Burkhard
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Date of publication of this fulltext: 25 Nov 2022 07:02

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A two-step protocol allowing the C−H amination of cyclic ethers with iminoiodinanes, followed by the reduction of the resulting intermediate has been developed for the preparation of amino alcohols. The initial C−H functionalization is accelerated by visible light, improving the reactivity compared to the thermal process performed in the dark. The effect of different substituents on the ...


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