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Na₇RbTl₄ – A New Ternary Zintl Phase Containing [Tl₄ ] ⁸⁻ Tetrahedra

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Schwinghammer, Vanessa F. ; Janesch, Melissa ; Korber, Nikolaus ; Gärtner, Stefanie
Date of publication of this fulltext: 20 Dec 2022 06:47

This publication is part of the DEAL contract with Wiley.


Na7RbTl4 has been prepared by solid state reaction from the elements. Single crystal X-ray structure analysis suggested the presence of pseudo-merohedral twinning. The final model could be derived in space group Pbam (a=16.3584(4) angstrom, b=16.3581(4) angstrom, c=11.3345(3) angstrom, V=3033.04(14) angstrom(3), R-1/wR(2) 0.0282/0.0402) and proved the presence of isolated [Tl-4](8-) anions, which ...


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