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Synthetic Application of Bismuth LMCT Photocatalysis in Radical Coupling Reactions

Birnthaler, Dominik ; Narobe, Rok ; Lopez-Berguno, Eliseo ; Haag, Christoph ; König, Burkhard


Ligand-to-metal charge transfer (LMCT) photocatalysis allows the activation and synthetic utilization of halides and other heteroatoms in metal complexes. Many metals are known to undergo LMCT but so far remain underutilized in the field of catalysis. A screening assay identifying LMCT activity helped us to expand this catalysis concept to the application of bismuth LMCT in organic radical ...


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