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Reactivity of E ₄ (E ₄ =P ₄ , As ₄ , AsP ₃ ) towards Low‐Valent Al(I) and Ga(I) Compounds

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Haimerl, Maria ; Piesch, Martin ; Yadav, Ravi ; Roesky, Peter W. ; Scheer, Manfred
Date of publication of this fulltext: 17 Jan 2023 05:57

This publication is part of the DEAL contract with Wiley.


The reactivity of yellow arsenic and the interpnictogen compound AsP3 towards low-valent group 13 compounds was investigated. The reactions of [LAl] (1, L=[{N(C6H3iPr2-2,6)C(Me)}2CH]−) with As4 and AsP3 lead to [(LAl)2(μ,η1:1:1:1-E4)] (E4=As4 (3 b), AsP3 (3 c)) by insertion of two fragments [LAl] into two of the six E−E edges of the E4 tetrahedra. Furthermore, the reaction of [LGa] (2) with E4 ...


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