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Coordination of Pnictogenylboranes Towards Tl(I) Salts and a Tl‐ Mediated P−P Coupling

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Szlosek, Robert ; Ackermann, Matthias T. ; Marquardt, Christian ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred
Date of publication of this fulltext: 24 Jan 2023 06:48


The coordination chemistry of only Lewis-base (LB)-stabilized pnictogenylboranes EH2BH2⋅NMe3 (E=P, As) towards Tl(I) salts has been studied. The reaction of Tl[BArCl] (BArCl=[B(3,5-C6H3Cl2)4]−) with the corresponding pnictogenylborane results in the formation of [Tl(EH2BH2⋅NMe3)][BArCl] (1 a: E=P; 1 b: E=As). Whereas the Tl ion in 1 a/b is monocoordinated, the exchange of the weakly coordinating ...


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