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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-536004
- DOI to cite this document:
- 10.5283/epub.53600
This publication is part of the DEAL contract with Wiley.
Abstract
The coordination chemistry of only Lewis-base (LB)-stabilized pnictogenylboranes EH2BH2 center dot NMe3 (E= P, As) towards Tl(I) salts has been studied. The reaction of Tl[BArCl] (BArCl=[B(3,5-C6H3Cl2)(4)]) with the corresponding pnictogenylborane results in the formation of [Tl(EH2BH2 center dot NMe3)][BArCl] (1a: E= P; 1b: E= As). Whereas the Tl ion in 1a/b is monocoordinated, the exchange of ...

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