Go to content
UR Home

Coordination of Pnictogenylboranes Towards Tl(I) Salts and a Tl‐ Mediated P−P Coupling

URN to cite this document:
urn:nbn:de:bvb:355-epub-536004
DOI to cite this document:
10.5283/epub.53600
Szlosek, Robert ; Ackermann, Matthias T. ; Marquardt, Christian ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred
Date of publication of this fulltext: 24 Jan 2023 06:48


Abstract

The coordination chemistry of only Lewis-base (LB)-stabilized pnictogenylboranes EH2BH2⋅NMe3 (E=P, As) towards Tl(I) salts has been studied. The reaction of Tl[BArCl] (BArCl=[B(3,5-C6H3Cl2)4]−) with the corresponding pnictogenylborane results in the formation of [Tl(EH2BH2⋅NMe3)][BArCl] (1 a: E=P; 1 b: E=As). Whereas the Tl ion in 1 a/b is monocoordinated, the exchange of the weakly coordinating ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons