Coordination chemistry of pnictogenylboranes towards group 6 transition metal Lewis acids

URN to cite this document:: urn:nbn:de:bvb:355-epub-538078
DOI to cite this document:: 10.5283/epub.53807

Lehnfeld, Felix ; Hegen, Oliver ; Balázs, Gábor ; Timoshkin, Alexey Y.

; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 21 Feb 2023 06:30

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Abstract

The coordination behavior of different pnictogenylboranes towards group 6 metal Lewis acids is investigated. The resulting complexes with phosphanylboranes [(CO)(4)M(PH2BH2 center dot NMe3)(2)] (M-Cr, Mo, W; 1-3), arsanylboranes ([(CO)(4)M(AsH2BH2 center dot NMe3)(2)] (M-Cr, Mo, W; 4-6) and tBu-substituted phosphanylboranes [(CO)(4)M(tBuPHBH(2)center dot NMe3)(2)] (M-Cr, W; 7-8) are fully ...