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Synthesis and Reactivity of a Cyclooctatetraene‐Like Polyphosphorus Ligand Complex [Cyclo‐P 8 ]

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Riesinger, Christoph ; Dielmann, Fabian ; Szlosek, Robert ; Virovets, Alexander V. ; Scheer, Manfred
Date of publication of this fulltext: 06 Apr 2023 09:29

This publication is part of the DEAL contract with Wiley.


The thermolysis of Cp′′′Ta(CO)4 with white phosphorus (P4) gives access to [{Cp′′′Ta}2(μ,η2 : 2 : 2 : 2 : 1 : 1-P8)] (A), representing the first complex containing a cyclooctatetraene-like (COT) cyclo-P8 ligand. While ring sizes of n >6 have remained elusive for cyclo-Pn structural motifs, the choice of the transition metal, co-ligand and reaction conditions allowed the isolation of A. Reactivity ...


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