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Across the Dimensions: A Three‐Component Self‐Assembly of Pentaphosphaferrocene‐based Coordination Polymers

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Grill, Kevin ; Dinauer, Sabrina B. ; Peresypkina, Eugenia ; Virovets, Alexander V. ; Scheer, Manfred
Date of publication of this fulltext: 18 Apr 2023 06:38

This publication is part of the DEAL contract with Wiley.


Pentaphosphaferrocenes [CpRFe(η5-P5)] (Cp*=η5-C5Me5) (A), Cp’’=η5-C5H3tBu2-1,3 (B)) are excellent building blocks for polymeric assemblies in supramolecular chemistry in combination with coinage metal salts of weakly coordinating anions such as AgSbF6. Adding rigid aromatic dinitriles ortho/meta/para-(NC)2C6H4 in a one-pot reaction between [CpRFe(η5-P5)] and AgSbF6 leads to various coordination ...


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