Across the Dimensions: A Three‐Component Self‐Assembly of Pentaphosphaferrocene‐based Coordination Polymers

URN to cite this document:: urn:nbn:de:bvb:355-epub-540781
DOI to cite this document:: 10.5283/epub.54078

Grill, Kevin ; Dinauer, Sabrina B. ; Peresypkina, Eugenia

; Virovets, Alexander V. ; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
PDF
Early View
(3MB)

Date of publication of this fulltext: 18 Apr 2023 06:38

Alternative links to fulltext:DOI Publisher

Details

Preview: Early View

Export bibliographical data

Abstract

Pentaphosphaferrocenes [CpRFe(η5-P5)] (Cp*=η5-C5Me5) (A), Cp’’=η5-C5H3tBu2-1,3 (B)) are excellent building blocks for polymeric assemblies in supramolecular chemistry in combination with coinage metal salts of weakly coordinating anions such as AgSbF6. Adding rigid aromatic dinitriles ortho/meta/para-(NC)2C6H4 in a one-pot reaction between [CpRFe(η5-P5)] and AgSbF6 leads to various coordination ...