Go to content
UR Home

Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs)

URN to cite this document:
urn:nbn:de:bvb:355-epub-541445
DOI to cite this document:
10.5283/epub.54144
Haimerl, Maria ; Schwarzmaier, Christoph ; Riesinger, Christoph ; Timoshkin, Alexey Y. ; Melaimi, Mohand ; Bertrand, Guy ; Scheer, Manfred
Date of publication of this fulltext: 03 May 2023 12:58


Abstract

Different cyclic (alkyl)(amino)carbenes (CAACs) were reacted with yellow arsenic. Several products [(CAAC-n)2(μ,η1:1-As2)] (n=1 (1), 4 (2)), [(CAAC-2)3(μ3,η1:1:1-As4)] (3) and [(CAAC-3)4(μ4,η1:1:1:1- As8)] (6) were isolated due to the differing steric properties of CAAC-1-4. The products contain As2, As4 or As8 units and represent the first examples of CAACs-substituted products of yellow ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons