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Reactivity of [Cp′′ 2 Zr(η 1:1 −E 4 )] (E=P, As) towards Nucleophiles

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Heinl, Veronika ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 04 May 2023 07:36


The functionalization of the polypnictogen ligand complexes [Cp′′2Zr(η1:1-E4)] (E=P (1 a), As (1 b); Cp′′=1,3-di-tertbutyl-cyclopentadienyl) is focused to modify the features of the polypnictogen unit to explore new synthetic pathways for further transformations. The reaction behavior of 1 towards main group nucleophiles is investigated. The reaction of 1 a with tBuLi leads to the ionic product ...


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