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Transformation of the cyclo ‐P 5 Middle Deck in [(Cp*Fe)(Cp’’’Co)(μ,η 5 :η 4 ‐P 5 )] upon Functionalization – A Comprehensive Study of Reactivity

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Dinauer, Sabrina B. ; Piesch, Martin ; Szlosek, Robert ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 11 May 2023 05:15

This publication is part of the DEAL contract with Wiley.


The heterobimetallic triple-decker complex [(Cp*Fe)(Cp’’’Co)(μ,η5 : η4-P5)] (1) was functionalized by main group nucleophiles and subsequently electrophilically quenched or oxidized. Reacting 1 with group 14 nucleophiles revealed different organo-substituted P5R middle-decks depending on the steric and electronic effects of the used alkali metal organyls (2: R=tBu; 3: R=Me). Further, with ...


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