Organometallic–Organic Hybrid Assemblies Featuring the Diantimony Complex [Cp 2 Mo 2 (CO) 4 (μ,η 2 ‐Sb 2 )], Ag I Ions and N‐Donor Molecules as Building Blocks

URN to cite this document:: urn:nbn:de:bvb:355-epub-542603
DOI to cite this document:: 10.5283/epub.54260

Shelyganov, Pavel A. ; Elsayed Moussa, Mehdi ; Seidl, Michael ; Scheer, Manfred

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Date of publication of this fulltext: 23 May 2023 06:02

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Abstract

The reactions of the organometallic ligand complex [Cp2Mo2(CO)4(μ,η2-Sb2)] (C) with Ag[TEF] ([TEF]−=[Al{OC(CF3)3}4]−) in the presence of a number of di- or polytopic N-donor molecules (1,6,7,12-tetraazaperylene (L1), 2,2’-bipyrimidine (L2), 4,4’-bipyridine (L3), trans-1,2-di(4-pyridyl)ethylene (L4) and 1,3-di(4-pyridyl)propane (L5)), were studied. Depending on the reaction stoichiometry and ...