Go to content
UR Home

Nucleophilic Attack at Pentaarsaferrocene [Cp*Fe(η5‐As5)]‐The Way to Larger Polyarsenide Ligands

URN to cite this document:
DOI to cite this document:
Reichl, Stephan ; Riesinger, Christoph ; Scheer, Manfred
Date of publication of this fulltext: 01 Aug 2023 05:03

This publication is part of the DEAL contract with Wiley.


By the reaction of [Cp*Fe(η5-As5)] (I) (Cp*=C5Me5) with main group nucleophiles, unique functionalized products with η4-coordinated polyarsenide (Asn) units (n=5, 6, 20) are obtained. With carbon-based nucleophiles such as MeLi or KBn (Bn=CH2Ph), the anionic organo-substituted polyarsenide complexes, [Li(2.2.2-cryptand)][Cp*Fe(η4-As5Me)] (1 a) and [K(2.2.2-cryptand)][Cp*Fe{η4-As5(CH2Ph)}] (1 b), ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons