A General Pathway towards NHC ⋅ GaH2(OTf) Adducts – The Key for the Synthesis of NHC‐Stabilized Cationic 13/15 Chain Compounds of Gallium - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-546035
DOI to cite this document:: 10.5283/epub.54603

Szlosek, Robert ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
PDF
Early View
(3MB)

Date of publication of this fulltext: 22 Aug 2023 08:21

Alternative links to fulltext:DOI Publisher

This publication is part of the DEAL contract with Wiley.

Details

Preview: Early View

Export bibliographical data

Abstract

A general pathway towards NHC (NHC=N-heterocyclic carbene)-stabilized galliummonotriflates NHC ⋅ GaH2(OTf) (NHC=IDipp, 1 a; IPr2Me2, 1 b; IMes, 1 c; IDipp=1,3-bis(2,6-diisopropylphenyl)-imidazolin-2-ylidene, IPr2Me2=1,3-bis-(diisopropyl)-4,5-dimethyl-imidazolin-2-ylidene, IMes=1,3-bis(2,4,6-trimethylphenyl)-imidazolin-2-ylidene) is reported. Quantum chemical calculations give detailed insight ...