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A General Pathway towards NHC ⋅ GaH2(OTf) Adducts – The Key for the Synthesis of NHC‐Stabilized Cationic 13/15 Chain Compounds of Gallium

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Szlosek, Robert ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 22 Aug 2023 08:21

This publication is part of the DEAL contract with Wiley.


A general pathway towards NHC (NHC=N-heterocyclic carbene)-stabilized galliummonotriflates NHC ⋅ GaH2(OTf) (NHC=IDipp, 1 a; IPr2Me2, 1 b; IMes, 1 c; IDipp=1,3-bis(2,6-diisopropylphenyl)-imidazolin-2-ylidene, IPr2Me2=1,3-bis-(diisopropyl)-4,5-dimethyl-imidazolin-2-ylidene, IMes=1,3-bis(2,4,6-trimethylphenyl)-imidazolin-2-ylidene) is reported. Quantum chemical calculations give detailed insight ...


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