Go to content
UR Home

Divergent and Synergistic Photocatalysis: Hydro- and Oxoalkylation of Vinyl Arenes for the Stereoselective Synthesis of Cyclopentanols via a Formal [4+1]-Annulation of 1,3-Dicarbonyls

URN to cite this document:
DOI to cite this document:
Katta, Narenderreddy ; Zhao, Quan-Qing ; Mandal, Tirtha ; Reiser, Oliver
Date of publication of this fulltext: 12 Sep 2023 15:56


The controllable divergent reactivity of 1,3-dicarbonyls is described, which enables the efficient hydro-and oxoalkylation of vinyl arenes. Both reaction pathways are initiated through the formation of polarity-reversed C-centered-radical intermediates at the active methylene center of 1,3-dicarbonyls via direct photocatalytic C-H bond transformations. The oxoalkylation of alkenes is achieved ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons