![]() | License: Creative Commons Attribution Non-commercial No Derivatives 4.0 Early View (1MB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-547159
- DOI to cite this document:
- 10.5283/epub.54715
This publication is part of the DEAL contract with Wiley.
Abstract
The reaction of the Lewis base-stabilized phosphinoborane monomer tBuHPBH(2)NMe(3) (2 a) with catalytic amounts of bis(eta(5):eta(1)-adamantylidenepentafulvene)titanium (1) provides a convenient new route to the polyphosphinoborane [tBuPH-BH2](n) (3 a). This method offers access to high molar mass materials under mild conditions and with short reaction times (20 degrees C, 1 h in toluene). It ...

Owner only: item control page