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Titanium‐Catalyzed Polymerization of a Lewis Base‐Stabilized Phosphinoborane

URN to cite this document:
urn:nbn:de:bvb:355-epub-547159
DOI to cite this document:
10.5283/epub.54715
Braese, Jens ; Lehnfeld, Felix ; Annibale, Vincent T. ; Oswald, Tim ; Beckhaus, Rüdiger ; Manners, Ian ; Scheer, Manfred
Date of publication of this fulltext: 20 Sep 2023 04:23

This publication is part of the DEAL contract with Wiley.


Abstract

The reaction of the Lewis base-stabilized phosphinoborane monomer tBuHPBH(2)NMe(3) (2 a) with catalytic amounts of bis(eta(5):eta(1)-adamantylidenepentafulvene)titanium (1) provides a convenient new route to the polyphosphinoborane [tBuPH-BH2](n) (3 a). This method offers access to high molar mass materials under mild conditions and with short reaction times (20 degrees C, 1 h in toluene). It ...

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