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Determination of femtosecond lifetimes of higher excited singlet states by means of transient photophysical hole-burning. The S2 state of phenanthrene

URN to cite this document:
urn:nbn:de:bvb:355-epub-55277
DOI to cite this document:
10.5283/epub.5527
Dick, Bernhard ; Nickel, Bernhard
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Date of publication of this fulltext: 05 Aug 2009 13:50


Abstract

Transient photophys. hole-burning was studied as a method of measuring femtosecond lifetimes of higher excited electronic states of polyat. mols. For the 0,0 transition to the S2 state of phenanthrene in isopentane/2-methylpentane glass at 4 K, a homogeneous linewidth of 67 +- 7 cm-1 was found corresponding to a lifetime of 79 +- 8 fs for this state.


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