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Characterization of the Ligand Properties of Donor‐stabilized Pnictogenyltrielanes

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Szlosek, Robert ; Niefanger, Amelie Sophie ; Balázs, Gábor ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred
Date of publication of this fulltext: 18 Jan 2024 06:35

This publication is part of the DEAL contract with Wiley.


A general synthesis and the characterization of novel alkyl-substituted NHC-stabilized pnictogenylboranes NHC ⋅ BH2ER2 (NHC=N-heterocyclic carbene, E=P, As; R2=Me2, Ph2, tBuH, Cy2, (SiMe3)2) are reported. These compounds were reacted with Ni(CO)4 to the corresponding complexes of the type [(NHC ⋅ BH2ER2)Ni(CO)3] to determine their donor strength by Tolman Electronic Parameters (TEPs) and their ...


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