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Characterization of the Ligand Properties of Donor‐stabilized Pnictogenyltrielanes

URN to cite this document:
urn:nbn:de:bvb:355-epub-553444
DOI to cite this document:
10.5283/epub.55344
Szlosek, Robert ; Niefanger, Amelie Sophie ; Balázs, Gábor ; Seidl, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred
Date of publication of this fulltext: 18 Jan 2024 06:35

This publication is part of the DEAL contract with Wiley.


Abstract

A general synthesis and the characterization of novel alkyl-substituted NHC-stabilized pnictogenylboranes NHC ⋅ BH2ER2 (NHC=N-heterocyclic carbene, E=P, As; R2=Me2, Ph2, tBuH, Cy2, (SiMe3)2) are reported. These compounds were reacted with Ni(CO)4 to the corresponding complexes of the type [(NHC ⋅ BH2ER2)Ni(CO)3] to determine their donor strength by Tolman Electronic Parameters (TEPs) and their ...

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