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NHC‐Stabilized Mixed Group 13/14/15 Element Hydrides

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Ackermann, Matthias T. ; Szlosek, Robert ; Riesinger, Christoph ; Seidl, Michael ; Timoshkin, Alexey Y. ; Rivard, Eric ; Scheer, Manfred
Date of publication of this fulltext: 18 Jan 2024 08:32

This publication is part of the DEAL contract with Wiley.


The syntheses of novel N-heterocyclic carbene (NHC) adducts of group 13, 14 and 15 element hydrides are reported. Salt metathesis reactions between NaPH2 and IDipp ⋅ GeH2BH2OTf (1) (IDipp=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) led to mixtures of the two isomers IDipp ⋅ GeH2BH2PH2 (2 a) and IDipp ⋅ BH2GeH2PH2 (2 b); by altering the reaction conditions an almost exclusive formation of ...


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