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Visible and Near UV Absorption Spectrum of Nitrosobenzene Isolated in Solid Argon: Maximum Entropy Analysis, Homogeneous Line Width of S2, and Semiempirical Electronic Structure Calculations

Engert, Jutta M. ; Slenczka, Alkwin ; Kensy, Uwe ; Dick, Bernhard



Abstract

The absorption spectrum of nitrosobenzene isolated in solid Ar was studied up to an energy of 45,000 cm-1. In this medium a previously unreported vibrational structure could be resolved for the 1st UV band with origin at 30,260 cm-1. This band is assigned to the S0 -> S2 transition. After numerical resoln. enhancement with the max. entropy method this vibrational structure could be analyzed in ...

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