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Visible and Near UV Absorption Spectrum of Nitrosobenzene Isolated in Solid Argon: Maximum Entropy Analysis, Homogeneous Line Width of S2, and Semiempirical Electronic Structure Calculations

Engert, Jutta M., Slenczka, Alkwin, Kensy, Uwe und Dick, Bernhard (1996) Visible and Near UV Absorption Spectrum of Nitrosobenzene Isolated in Solid Argon: Maximum Entropy Analysis, Homogeneous Line Width of S2, and Semiempirical Electronic Structure Calculations. Journal of Physical Chemistry 100 (29), S. 11883-11892.

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Zusammenfassung

The absorption spectrum of nitrosobenzene isolated in solid Ar was studied up to an energy of 45,000 cm-1. In this medium a previously unreported vibrational structure could be resolved for the 1st UV band with origin at 30,260 cm-1. This band is assigned to the S0 -> S2 transition. After numerical resoln. enhancement with the max. entropy method this vibrational structure could be analyzed in ...

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Dokumentenart:Artikel
Datum:1996
Zusätzliche Informationen (Öffentlich):CAN 125:70526 73-4 Optical, Electron, and Mass Spectroscopy and Other Related Properties 2396-01-2 (Phenyl radical); 10102-43-9 (Nitric oxide) Role: FMU (Formation, unclassified), FORM (Formation, nonpreparative) (formation in photolysis of nitrosobenzene); 586-96-9 (Nitrosobenzene) Role: PRP (Properties), RCT (Reactant), RACT (Reactant or reagent) (visible and near UV absorption spectrum and photolysis of argon solid-isolated); 7440-37-1 (Argon) Role: NUU (Other use, unclassified), USES (Uses) (visible and near UV absorption spectrum of nitrosobenzene isolated in solid)
Institutionen:Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Bernhard Dick
Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof Dr. Alkwin Slenczka
Identifikationsnummer:
WertTyp
1996:382860Andere
Stichwörter / Keywords:Electronic structure (of nitrosobenzene); Ultraviolet and visible spectra (of nitrosobenzene isolated in solid argon); Ultraviolet and visible spectra (near-UV, of nitrosobenzene isolated in solid argon); Bleaching (photochem., of nitrosobenzene); Energy level transition (radiative, lifetimes, of nitrosobenzene); nitrosobenzene solid argon UV electronic structure
Dewey-Dezimal-Klassifikation:500 Naturwissenschaften und Mathematik > 540 Chemie
Status:Veröffentlicht
Begutachtet:Ja, diese Version wurde begutachtet
An der Universität Regensburg entstanden:Ja
Eingebracht am:19 Jan 2009 13:48
Zuletzt geändert:24 Mai 2018 10:11
Dokumenten-ID:5536
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