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Electrophilic Functionalization of a Hexaphosphabenzene Ligand in [(Cp*Mo)₂(μ,η⁶ : ⁶‐P₆)]

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Widmann, Maximilian ; Riesinger, Christoph ; Szlosek, Robert ; Balázs, Gábor ; Scheer, Manfred
Date of publication of this fulltext: 20 Feb 2024 07:00

This publication is part of the DEAL contract with Wiley.


The electrophilic functionalization of the triple-decker sandwich complex [{Cp*Mo}2(μ,η6:6-P6)] (A) and its mono-oxidized counterpart [{Cp*Mo}2(μ,η6:6-P6)][SbF6] (B) with reactive main-group electrophiles as well as radical scavengers is shown to be a reliable method for the selective functionalization of the hexaphosphabenzene ligand. Depending on the electrophile used, the regioselectivity of ...


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