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Accelerated photochemical reactions at oil-water interface exploiting melting point depression

Tian, Ya-Ming ; Silva, Wagner ; Gschwind, Ruth Maria ; König, Burkhard


Water can accelerate a variety of organic reactions far beyond the rates observed in classical organic solvents. However, using pure water as a solvent introduces solubility constraints that have limited the applicability of efficient photochemistry in particular. We report here the formation of aggregates between pairs of arenes, heteroarenes, enamines, or esters with different electron ...


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