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Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis

Grotjahn, Sascha ; Graf, Christina ; Zelenka, Jan ; Pattanaik, Aryaman ; Müller, Lea ; Kutta, Roger Jan ; Rehbein, Julia ; Roithová, Jana ; Gschwind, Ruth M. ; Nuernberger, Patrick ; König, Burkhard



Abstract

Photocatalytic reactions involving a reductive radical-polar crossover (RRPCO) generate intermediates with carbanionic reactivity. Many of these proposed intermediates resemble highly reactive organometallic compounds. However, conditions of their formation are generally not tolerated by their isolated organometallic versions and often a different reactivity is observed. Our investigations on ...

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