Reactivity of Superbasic Carbanions Generated via Reductive Radical‐Polar Crossover in the Context of Photoredox Catalysis

URN to cite this document:: urn:nbn:de:bvb:355-epub-556129
DOI to cite this document:: 10.5283/epub.55612

Grotjahn, Sascha ; Graf, Christina ; Zelenka, Jan ; Pattanaik, Aryaman ; Müller, Lea ; Kutta, Roger Jan

; Rehbein, Julia

; Roithová, Jana ; Gschwind, Ruth M.

; Nuernberger, Patrick

; König, Burkhard

License: Creative Commons Attribution 4.0
PDF - Published Version
(8MB)

Date of publication of this fulltext: 01 Mar 2024 05:18

Alternative links to fulltext:DOI Publisher

This publication is part of the DEAL contract with Wiley.

Details

Preview

Export bibliographical data

Abstract

Photocatalytic reactions involving a reductive radical-polar crossover (RRPCO) generate intermediates with carbanionic reactivity. Many of these proposed intermediates resemble highly reactive organometallic compounds. However, conditions of their formation are generally not tolerated by their isolated organometallic versions and often a different reactivity is observed. Our investigations on ...