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Redox properties of LOV domains: chemical versus photochemical reduction, and influence on the photocycle

Noell, Gilbert ; Hauska, Guenter ; Hegemann, Peter ; Lanzl, Karin ; Noell, Tanja ; von Sanden-Flohe, Madlene ; Dick, Bernhard


LOV (light-oxygen-voltage-sensitive) domains comprise the light-sensitive parts of many blue light photoreceptor proteins. Photo-excitation of the chromophore FMN in these LOV domains leads to formation of a covalent adduct between FMN and a cysteine residue. So far, the electronically excited singlet and triplet states of FMN have been identified as the only intermediates in the photocycles of ...


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