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Electro‐mediated PhotoRedox Catalysis for Selective C(sp3)–O Cleavages of Phosphinated Alcohols to Carbanions

Tian, Xianhai ; Karl, Tobias A. ; Reiter, Sebastian ; Yakubov, Shahboz ; de Vivie‐Riedle, Regina ; König, Burkhard ; Barham, Joshua P.




Abstract

We report a novel example of electro-mediated photoredox catalysis (e-PRC) in the reductive cleavage of C(sp(3))-O bonds of phosphinated alcohols to alkyl carbanions. As well as deoxygenations, olefinations are reported which are E-selective and can be made Z-selective in a tandem reduction/photosensitization process where both steps are photoelectrochemically promoted. Spectroscopy, computation, ...

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