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Synthesis of a carborane-substituted bis(phosphanido) cobaltate(i), ligand substitution, and unusual P4fragmentation

Coburger, Peter ; Leitl, Julia ; Scott, Daniel J. ; Hierlmeier, Gabriele ; Shenderovich, Ilya G. ; Hey-Hawkins, Evamarie ; Wolf, Robert


Oxidative addition of the P-P single bond of an ortho-carborane-derived 1,2-diphosphetane (1,2-C-2(PMes)(2)B10H10) (Mes = 2,4,6-Me3C6H2) to cobalt(-i) and nickel(0) sources affords the first heteroleptic complexes of a carborane-bridged bis(phosphanido) ligand. The complexes also incorporate labile ligands suitable for further functionalisation. Thus, the cobalt(i) complex ...


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