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Chirality of the Conformation Attacks the Planarity of the sp2 Carbon Atom in a Covalent Bond

Brunner, Henri ; Ikeshita, Masahiro ; Tsuno, Takashi



Abstract

The correlation of the rotation about the bond C'-C-alpha and the pyramidalization of the sp(2) hybridized carbon atom C' and its three bonding partners to a flattened tetrahedron was investigated for the substructure C-beta-C alpha H-C'(=O)-OMe. A search in the Cambridge Structural Database (CSD) gave 15,295 structures with a substituted methyl acetate group at the end of the molecules. The ...

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