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Synthesis and Electrochemical Properties of Tetrasubstituted Tetraphenylethenes

DOI to cite this document:
10.5283/epub.56
Schreivogel, Alina ; Maurer, Jörg ; Winter, Rainer ; Baro, Angelika ; Laschat, Sabine
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Date of publication of this fulltext: 05 Aug 2009 13:21


Abstract

Tetrakis(4-acetoxy- and 4-benzoyloxyphenyl)ethenes 1f,g were obtained by acylation of tetrakis(4-hydroxyphenyl)ethene 1b. Ullmann etherification of 4,4’-dihydroxybenzophenone 2b and subsequent McMurry coupling yielded tetrakis(phenoxyphenyl)ethene 1i. The tetrakis( acetamidophenyl)ethene 1h was prepared in three steps from tetraphenylethene 1c via nitration, Raney-Ni reduction and acetylation. ...

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