Synthesis of Unprecedented 4d/4f‐Polypnictogens

URN to cite this document:: urn:nbn:de:bvb:355-epub-562951
DOI to cite this document:: 10.5283/epub.56295

Reinfandt, Niklas ; Schoo, Christoph

; Dütsch, Luis ; Köppe, Ralf ; Konchenko, Sergey N. ; Scheer, Manfred

; Roesky, Peter W.

License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 29 Feb 2024 12:27

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Abstract

A series of 4d/4f-polyarsenides, -polyarsines and -polystibines was obtained by reduction of the Mo-pnictide precursor complexes [{(CpMo)-Mo-t(CO)(2)}(2)(mu,eta(2:2)-E-2)] (E=As, Sb; Cp-t=tBu substituted cyclopentadienyl) with two different divalent samarocenes [Cp*Sm-2] and [(Cp-Me4nPr)(2)Sm]. For the reductive conversion of the Mo-stibide only one product was isolated, featuring a planar ...