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Divinylphenylene bridged diruthenium complexes bearing Ru(CO)Cl(PiPr3)2 entities

Maurer, Jörg, Sarkarb, Biprajit, Schwederskib, Brigitte, Kaimb, Wolfgang, Winter, Rainer F. and Zálišc, Stanislav (2006) Divinylphenylene bridged diruthenium complexes bearing Ru(CO)Cl(PiPr3)2 entities. Organometallics. (In Press)

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Date of publication of this fulltext: 05 Aug 2009 13:21

Abstract

Divinylphenylene bridged diruthenium complexes E,E-[{(PiPr3)2(CO)ClRu}2(µ-HC=CH-C6H4-CH=CH-1,3)] (m-2) and E,E-[{(PiPr3)2(CO)ClRu}2(µ-HC=CH-C6H4-CH=CH-1,4)] (p- 2) have been prepared and compared to their PPh3 containing analogues m-1 and p-1. The higher electron density at the metal atoms increases the contribution of the metal end groups to the bridge-dominated occupied frontier orbitals and ...

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Item type:Article
Date:2006
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Keywords:ruthenium; electrochemistry; spectroelectrochemistry; vinyl complexes
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:In Press
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:57
Owner only: item control page

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