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Divinylphenylene bridged diruthenium complexes bearing Ru(CO)Cl(PiPr3)2 entities

DOI to cite this document:
10.5283/epub.57
Maurer, Jörg ; Sarkarb, Biprajit ; Schwederskib, Brigitte ; Kaimb, Wolfgang ; Winter, Rainer F. ; Zálišc, Stanislav
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Date of publication of this fulltext: 05 Aug 2009 13:21


Abstract

Divinylphenylene bridged diruthenium complexes E,E-[{(PiPr3)2(CO)ClRu}2(µ-HC=CH-C6H4-CH=CH-1,3)] (m-2) and E,E-[{(PiPr3)2(CO)ClRu}2(µ-HC=CH-C6H4-CH=CH-1,4)] (p- 2) have been prepared and compared to their PPh3 containing analogues m-1 and p-1. The higher electron density at the metal atoms increases the contribution of the metal end groups to the bridge-dominated occupied frontier orbitals and ...

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