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Pseudo‐Octahedral Iron(II) Complexes with Near‐Degenerate Charge Transfer and Ligand Field States at the Franck‐Condon Geometry

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Moll, Johannes ; Naumann, Robert ; Sorge, Lukas ; Förster, Christoph ; Gessner, Niklas ; Burkhardt, Lukas ; Ugur, Naz ; Nuernberger, Patrick ; Seidel, Wolfram ; Ramanan, Charusheela ; Bauer, Matthias ; Heinze, Katja
Date of publication of this fulltext: 29 Feb 2024 12:56


Increasing the metal-to-ligand charge transfer (MLCT) excited state lifetime of polypyridine iron(II) complexes can be achieved by lowering the ligand's pi* orbital energy and by increasing the ligand field splitting. In the homo- and heteroleptic complexes [Fe(cpmp)(2)](2+) (1(2+)) and [Fe(cpmp)(ddpd)](2+) (2(2+)) with the tridentate ligands 6,2''-carboxypyridyl-2,2'-methylamine-pyridyl-pyridine ...


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