Oligomer and Polymer: Self Assembly of [Cp*Fe(η5‐P5)] and Ag(I) Salts of Bulky Weakly Coordinating Anions

URN to cite this document:: urn:nbn:de:bvb:355-epub-583659
DOI to cite this document:: 10.5283/epub.58365

Mondal, Bijan

; Riesinger, Christoph ; Fleischmann, Martin ; Scheer, Manfred

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 31 May 2024 15:20

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Abstract

Reactions between the five-fold symmetric building block [Cp*Fe(η5-P5)] (A) and Ag(I) salts containing bulky weakly coordinating anions [TEF] and [FAL] ([TEF] = [Al{OC(CF3)3}4]–, [FAl] = [FAl{OC6F10(C6F5)}3]–) are presented. While, in the presence of Ag[TEF], A leads to the formation of a hitherto condensed 1D coordination polymer [{Ag( η 2 : η 1 -A)2}]n[TEF]n (1), a new finite tetranuclear Ag(I) ...