Functionalization of Tetraphosphido Ligands by Heterocumulenes

URN to cite this document:: urn:nbn:de:bvb:355-epub-586207
DOI to cite this document:: 10.5283/epub.58620

Hauer, Sebastian

; Balázs, Gábor

; Gliese, Fabian ; Meurer, Florian

; Horsley Downie, Thomas M.

; Hennig, Christoph

; Weigand, Jan J. ; Wolf, Robert

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 08 Jul 2024 07:44

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Abstract

Although numerous polyphosphido complexes have been accessed through the transition-metal-mediated activation and functionalization of white phosphorus (P4), the selective functionalization of the resulting polyphosphorus ligands in these compounds remains underdeveloped. In this study, we explore the reactions between cyclotetraphosphido cobalt complexes and heterocumulenes, leading to ...