Potential of Mixed Dipnictogen Molybdenum Complexes in the Self-Assembly of Thallium Coordination Compounds

URN to cite this document:: urn:nbn:de:bvb:355-epub-586287
DOI to cite this document:: 10.5283/epub.58628

Zimmermann, Lisa ; Riesinger, Christoph ; Scheer, Manfred

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Date of publication of this fulltext: 08 Jul 2024 15:35

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Abstract

The coordination chemistry of the homo- and heterodipnictogen tetrahedrane complexes [{CpMo(CO)2}2(μ,η2:2-EE′)] (E, E′ = P, As, Sb) (A–F) toward Tl[BArF24] ([BArF24]− = [B(3,5-C6H3(CF3)2)4]−) was studied. Controlled by the used tetrahedranes A–F, and thus depending on the respective pnictogen atoms, the monomers [Tl(η2-A)][BArF24] ([A]Tl) and [Tl(η2-B)][BArF24] ([B]Tl), the double substituted ...