Controlled aggregation of a 1,3-diphosphacyclobutadiene complex in the coordination sphere of Ag(I) and Au(I) ions

URN to cite this document:: urn:nbn:de:bvb:355-epub-592818
DOI to cite this document:: 10.5283/epub.59281

Elsayed Moussa, Mehdi ; Rummel, Eva-Maria ; Heinl, Veronika ; Riesinger, Christoph ; Scheer, Manfred

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Date of publication of this fulltext: 02 Oct 2024 05:54

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Abstract

Reactions of the 1,3-diphosphete complex [Cp'''Co(η4-P2C2tBu2)] (Cp''' = Cp(tBu)3, 1) with Ag[Al{OC(CF3)3}4] (Ag[TEF]) and [LAu][TEF] (L = (THT)2, (THT)PPh3) were studied under various reaction conditions. Depending on the stoichiometry of the reactants, reaction time and temperature involved, a selective formation of the monomers, [{(Et2O)Ag}{Cp'''Co(µ,η4:η1:η1-P2C2tBu2)}][TEF] (4) and ...