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Versatile structures of group 13 metal halide complexes with 4,4′-bipy: from 1D coordination polymers to 2D and 3D metal–organic frameworks

Sevastianova, Tatiana N. ; Bodensteiner, Michael ; Maulieva, Albina F. ; Davydova, Elena I. ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Balázs, Gábor ; Graßl, Christian ; Seidl, Michael ; Scheer, Manfred ; Frenking, Gernot ; Berezovskaya, Ekaterina A. ; Kazakov, Igor V. ; Khoroshilova, Olesya V. ; Timoshkin, Alexey Y.



Zusammenfassung

A systematic structural study of complexes formed by aluminium and gallium trihalides with 4,4'-bipyridine (bipy) in 2 : 1, 1 : 1, and 1 : 2 stoichiometric ratios has been performed. Molecular structures of 11 complexes in the solid state have been determined for the first time. Complexes of 2 : 1 composition are molecular, while complexes of 1 : 1 composition form metal-organic frameworks of ...

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