Abstract
Unprecedented functionalized products with an eta(4)-P-5 ring are obtained by the reaction of [Cp* Fe(eta(5)-P-5)] (1; Cp*=eta(5)-C5Me5) with different nucleophiles. With LiCH2SiMe3 and LiNMe2, the monoanionic products [Cp*Fe(eta(4)-P5CH2SiMe3)](-) and [Cp*Fe(eta(4)-P5NMe2)](-), respectively, are formed. The reaction of 1 with NaNH2 leads to the formation of the trianionic compound ...
Abstract
Unprecedented functionalized products with an eta(4)-P-5 ring are obtained by the reaction of [Cp* Fe(eta(5)-P-5)] (1; Cp*=eta(5)-C5Me5) with different nucleophiles. With LiCH2SiMe3 and LiNMe2, the monoanionic products [Cp*Fe(eta(4)-P5CH2SiMe3)](-) and [Cp*Fe(eta(4)-P5NMe2)](-), respectively, are formed. The reaction of 1 with NaNH2 leads to the formation of the trianionic compound [{Cp*Fe(eta(4)-P-5)}(2)N](3-), whereas the reaction with LiPH2 yields [Cp*Fe(eta(4)-P5PH2)](-) as the main product, with {[Cp*Fe(eta(4)-P-5)](2)PH}(2-) as a byproduct. The calculated energy profile of the reactions provides a rationale for the formation of the different products.
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