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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-61522
- DOI to cite this document:
- 10.5283/epub.6152
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Abstract
The reaction of [2.2]paracyclophane (1) with liquid bromine affords a 1:1 mixture of only two isomeric products, the pseudo-para 2 and pseudo-ortho tetrabromide 3. The structure of the pseudo-para isomer 2 has been determined by X-ray structure analysis. Fourfold palladium-catalyzed coupling with styrenes and with methyl acrylate converts 2 and 3 into double-layered derivatives as e.g. 6a, 7a, ...
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