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pH Controlled Emission of Ruthenium(II)-tris-bipyridine Complexes

De Cola, L. ; Prodi, L. ; Zaccheroni, N. ; König, B.



Zusammenfassung

Ruthenium tris–2,2′-bipyridine complexes 1, 2 and 3 have additional non-coordinated basic pyridine or bipyridine moieties within their structures. Upon protonation they reversibly become suitable acceptor sites for intramolecular photoinduced electron transfer by which the ruthenium tris–2,2′-bipyridine emission is quenched. The pH dependent emission was studied in organic solvents and ...

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