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Synthesis and Structure of a Stabilized 10-Membered Cyclic Enediyne

Pitsch, W., Klein, M., Zabel, M. and König, B. (2002) Synthesis and Structure of a Stabilized 10-Membered Cyclic Enediyne. J. Org. Chem. 67, 6805 - 6807.

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The synthesis and structure of an acetal protected 10-membered cyclic enediyne-1,2-diol rac-10 is reported. The conformational constrain of the unsaturated macrocycle by the acetal protection group prevents the thermal cyclization reaction of the endiyne during synthesis and purification.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
Identification Number:
12227813PubMed ID
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6224
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