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Synthesis and Structure of Cyclen Hydroxylamine Ligands and their Zinc(II)Complexes

Reichenbach-Klinke, R., Zabel, M. and König, B. (2003) Synthesis and Structure of Cyclen Hydroxylamine Ligands and their Zinc(II)Complexes. J. Chem. Soc., Dalton Trans, 141 - 145.

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The synthesis of two new zinc(II) complexes with 1,4,7,10-tetraazacyclododecan-1-ol and 1,4,7,10-tetraazacyclododecan-1,7-diol as ligands is described. One of these complexes is characterized by X-ray structure analysis. By coordination to the metal cation the acidity of the hydroxylamine groups of the ligands is significantly increased as confirmed by potentiometric pH titrations.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Projects:GRK 640 Sensory photoreceptors in natural and artificial systems
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6229
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