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Electronic Effects on the Bergman Cyclisation of Enediynes. A Review

Klein, M., Walenzyk, T. and König, B. (2004) Electronic Effects on the Bergman Cyclisation of Enediynes. A Review. Collect. Czech. Chem. Commun. 69, 945 – 965.

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The thermal cyclisation of enediynes to benzene-1,4-diyl diradicals (Bergman cyclisations) is affected by geometrical and electronic conditions. While the effect of ring strain or conformational constrains on the cyclisation temperature has been investigated in detail, electronic contributions have been less studied. Often geometrical and electronic contributions cannot be clearly distinguished. ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
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Keywords:Enediynes, Bergman cyclisations, Electronic substituent effects, Alkynes, DNA cleavage agents, Antibiotics, Cytotoxic compounds
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6239
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