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Synthesis and peptide binding properties of methoxypyrrole amino acids (MOPAS).

Bonauer, C. ; Zabel, M. ; König, B.


Methoxypyrrole amino acids (MOPAS) have been prepared and were introduced into small peptides with hairpin structures. The intra- and intermolecular binding properties of this heterocyclic amino acid mimicking a dipeptido beta-strand was investigated by NMR titration and X-ray crystal structure analysis. The data reveal a hydrogen bonding pattern that is complementary to a peptide beta-sheet.

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