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Enhanced Peptide β-Sheet Affinity by Metal to Ligand Coordination

Kruppa, M. ; Bonauer, C. ; Michlová, V. ; König, B.


A histidine-coordinating metal complex substituted with methoxypyrrole amino acids (MOPAS) as a peptide β-sheet binder shows high affinity for a H2N−His-Leu-Leu-Val-Phe-OMe pentapeptide in DMSO solution. Within the complex, a β-sheet conformation is induced into the pentapeptide by weak intra-assembly interactions with the MOPAS units.

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